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Kinetics of the anion-catalyzed Michael reaction of silyl ketene acetals. Initiation and propagation steps of group transfer polymerization
Brittain
, p. 7440 - 7444 (2007/12/18)
The kinetics of the first three steps of ″group transfer polymerization″ (GTP) have been studied by stopped-flow FT-IR spectroscopy. The kinetic orders of the reaction of dimethylketene methyl trimethylsilyl acetal (1) with methyl methacrylate (MMA) have
