116255-48-2 Usage
Uses
Different sources of media describe the Uses of 116255-48-2 differently. You can refer to the following data:
1. Agricultural fungicide.
2. Bromuconazole is used on winter wheat and barley for the control
of foliar mildews, rusts and other diseases.
Definition
ChEBI: A member of the class of oxolanes carrying 1,2,4-triazol-ylmethyl and 2,4-dichlorophenyl substituents at position 2 as well as a bromo substituent at position 4. A foliar applied conazole fungicide for a range of crops including cereals, fruit, vegetables
and vines.
Metabolic pathway
Bromuconazole is a relatively stable compound which is not readily
hydrolysed, is quite persistent in soil and is subject to relatively slow
photodegradation. It is metabolised in plants but the parent compound
tends to be the major residue. However, bromuconazole is almost completely
metabolised in animals and birds (chickens) and its metabolites
are rapidly eliminated.
As with many other triazole fungicides, metabolism is very complex.
Bromuconazole exists in four forms (two diastereoisomeric pairs). There
are numerous sites available for biotransformation (lack of regioselectivity)
and there is also a lack of stereoselectivity at most sites. For example,
there are also four forms of metabolite 5 (4-hydroxybromuconazole) (two
diastereoisomeric pairs as with bromuconazole itself). Oxidation of
secondary alcohols to ketones and the thiolation of certain sites further
complicate the picture. Thiolation presumably occurs via the involvement
of glutathione but mercapturic acid conjugates (N-acetylcysteines)
do not appear to have been isolated.
Bromuconazole has been the subject of an evaluation by the Pesticide
Safety Directorate of UK MAFF. All of the information presented below is
derived from this source (PSD, 1996). All reported radiolabelled studies
were conducted using [14C-phenyl]bromuconazole.
Degradation
Bromuconazole was found to be stable in buffer at pH 5,7 and 9 at 25 °C
over 30 days.
Aqueous photolysis using filtered light to simulate mid-summer sun at
50" N conducted at 25 °C and pH 4 caused slow photodegradation. The
DT50 of bromuconazole was 18.2 days. Over 28 days a 10% yield of CO2
was obtained and six or more photoproducts were detected with none
accounting for more than 8% of the total. No degradation occurred in dark
controls.
Check Digit Verification of cas no
The CAS Registry Mumber 116255-48-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,6,2,5 and 5 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 116255-48:
(8*1)+(7*1)+(6*6)+(5*2)+(4*5)+(3*5)+(2*4)+(1*8)=112
112 % 10 = 2
So 116255-48-2 is a valid CAS Registry Number.
InChI:InChI=1/C13H12BrCl2N3O/c14-9-4-13(20-5-9,6-19-8-17-7-18-19)11-2-1-10(15)3-12(11)16/h1-3,7-9H,4-6H2
116255-48-2Relevant articles and documents
SUBSTITUTED SPIROCYCLIC KETOENOLS
-
, (2008/06/13)
The present invention relates to novel substituted spirocyclic ketoenols of the formula (I) in which W, X, Y, Z, A, B, D and G are as defined in the disclosure, to a plurality of processes for their preparation and to their use as pesticides, microbicides and herbicides.
Use of oxabicyclo[2.2.1]heptane derivatives as pesticidal agents
-
, (2008/06/13)
7-oxabicyclo[2.2.1]heptane derivatives of formula (I) in which X, R1, R2, R3 and R4 have the meanings set forth in the specification, are very suitable for controlling undesired microorganisms and animal pests. New 7-oxabicyclo[2.2.1]heptane derivatives of formula (Ia) in which X, R1, R2, R3 and R14 have the meanings set forth in the specification, and a process for the preparation of the new compounds.
Heterocyclic fluoroalkenyl thioethers and the use thereof as pesticides(III)
-
, (2008/06/13)
The present invention relates to novel heterocyclic fluoroalkenyl thioethers of the formula (I) in which X represents hydrogen, halogen or alkyl, m represents integers from 3 to 10, n represents 0, 1 or 2, Y represents sulphur or oxygen, R1 represents halogen, represents in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkenyl, alkenyloxy, alkenylthio or alkylcarbonyl, represents optionally substituted cycloalkyl, represents optionally substituted aryl or represents optionally substituted heterocyclyl and R2 represents hydrogen, halogen, represents in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkenyl, alkenyloxy, alkenylthio or alkylcarbonyl, represents optionally substituted cycloalkyl, represents optionally substituted aryl or represents optionally substituted heterocyclyl, ?except for compounds where R1=alkyl, Y=oxygen and X=hydrogen, and to processes for their preparation and to their use as pesticides.