116270-34-9Relevant academic research and scientific papers
Palladium-catalyzed hydroselenation of allenes with benzeneselenol
Ogawa, Akiya,Kudo, Atsuko,Hirao, Toshikazu
, p. 5213 - 5216 (1998)
Palladium(II) acetate (Pd(OAc)2) catalyzes the addition of benzeneselenol to allenes, providing the corresponding vinylic selenides in good yields. In contrast to the oxygen-induced radical addition of PhSell to terminal allenes, which occurred at the terminal double bond preferentially, the present palladium-catalyzed hydroselenation to terminal allenes affords the internal adduct preferentially; thus, these two reactions are complementary to each other for the synthesis of vinylic selenides.
Oxigen Induced Free-Radical Addition of Benzeneselenol to Allenes
Masawaki, Teruyuki,Ogawa, Akiya,Kambe, Nobuaki,Ryu, Ilhyong,Sonoda, Noboru
, p. 2407 - 2408 (2007/10/02)
The addition of benzeneselenol to mono- and disubstituted allenes proceeded in the presence of oxygen to give vinyl selenides in exellent yields.This reaction is likely to involve a radical chain process initiated by oxygen.
