116301-02-1Relevant articles and documents
Synthesis and Absolute Sterochemistry of the Two Diasteromers of P3-1-(2-Nitrophenyl)ethyl Adenosine Triphosphate ("Caged" ATP)
Corrie, John E. T.,Reid, Gordon P.,Trentham, David R.,Hursthouse, Michael B.,Mazid, Muhammed A.
, p. 1015 - 1020 (1992)
1-(2-Nitrophenyl)ethanol was resolved by fractional crystallisation of its diastereoisomeric (1S)-camphanates.The absolute stereochemistry of the (S)-alcohol was determined using the Horeau kinetic resolution procedure, and subsequently confirmed by X-ray crystallography of its (1S)-camphanate ester.The resolved alcohols were converted to (R)- and (S)-1-(2-nitrophenyl)ethyl phosphates, each of which was condensed with adenosine diphosphate to give the (R)- and (S)-1-(2-nitrophenyl)ethyl P3-esters of adenosine triphosphate.