116329-69-2

Upstream product

• 116329-65-8 (1R,7aR)-7a-Methyl-1-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-1,2,5,6,7,7a-hexahydro-inden-4-one 
• 55812-80-1 (1R,3aR,7aR)-7a-Methyl-1-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-octahydro-inden-4-one 
• 116329-68-1 (1R,5R,7aR)-5-((S)-4-Methoxy-1-methyl-cyclohexa-2,4-dienyl)-7a-methyl-1-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-1,2,5,6,7,7a-hexahydro-inden-4-one 

Relevant academic research and scientific papers

HETEROSTEROIDS VIA ORGANOIRON COMPLEXES: ENANTIOSELECTIVE SYNTHESIS OF THE 9-(4-KETO-1-METHYLCYCLOHEX-2-ENYL)-8-KETO-DES-AB-ERGOSTA-14,15-22,23-DIENE; AN EASY RREARRANGEMENT OF THE TITLE COMPOUND INTO A 6-OXA B-NOR HETEROSTEROID STRUCTURE

The synthesis via organoiron complexes of the chiral 9-(4-keto-1-methylcyclohex-2-enyl)-8-keto-des-AB-ergosta-14,15-22,23-diene 13, as well as the rearrangement of 4, 13 to 6-oxa B-nor heterosteroids are described.