116332-65-1Relevant academic research and scientific papers
Organocatalytic Redox Isomerization of Electron-Deficient Allylic Alcohols: Synthesis of 1,4-Ketoaldehydes
Mondal, Keshab,Mondal, Buddhadeb,Pan, Subhas Chandra
, p. 4835 - 4840 (2016/07/06)
An organocatalytic redox isomerization strategy has been developed for the synthesis of 1,4-ketoaldehydes. DABCO was found to be the best catalyst for the isomerization of -hydroxy enones. With 20 mol % of DABCO as catalyst and DMSO as the solvent high yi
NEW METHODS FOR THE SYNTHESIS OF 2-ARYLPYRROLES
Kruse, Chris G.,Bouw, Jan P.,Hes, Roelof van,Kuilen, Aalt van de,Hartog, Jack A. J. den
, p. 3141 - 3151 (2007/10/02)
Two short and efficient synthetic approaches for -mostly unknown- 2-arylpyrroles are presented.The key intermediates 3 are conveniently obtained from commercially available acetophenones 5 (method I) or benzoic acid derivatives 10, 11 (method II).
