116382-01-5

Upstream product

• 116381-98-7 [(1R,2R,5S)-2-(2-Chloro-ethyl)-3-methyl-bicyclo[3.2.1]oct-3-en-1-yl]-acetic acid methyl ester 
• 116381-94-3 [(1S,5R,6R)-6-((E)-4-Methoxymethoxy-1-methyl-but-1-enyl)-bicyclo[3.1.0]hex-(3E)-ylidene]-acetic acid methyl ester 
• 116381-95-4 [(1S,5S,6S)-6-((E)-4-Methoxymethoxy-1-methyl-but-1-enyl)-bicyclo[3.1.0]hex-2-en-3-yl]-acetic acid methyl ester 
• 116381-93-2 tert-Butyl-[(1S,3S,5R,6R)-6-((E)-4-methoxymethoxy-1-methyl-but-1-enyl)-bicyclo[3.1.0]hex-3-yloxy]-dimethyl-silane 
• 116381-99-8 (3aS,6S,8aS)-8-Methyl-2,3,4,5,6,8a-hexahydro-1H-3a,6-methano-azulene-3-carboxylic acid methyl ester 
• 116382-13-9 (1S,7S,10R)-8-Methyl-4-oxa-tricyclo[8.2.1.0^1,7]tridec-8-en-3-one 
• 116381-91-0 tert-Butyl-((1S,5R)-6,6-dichloro-bicyclo[3.1.0]hex-3-yloxy)-dimethyl-silane 
• 116381-92-1 tert-Butyl-((1S,3S,5R,6S)-6-chloro-bicyclo[3.1.0]hex-3-yloxy)-dimethyl-silane 
• 101533-94-2 3-pentyn-1-ol methoxymethyl ether 
• 116382-16-2 (E)-2-Iodo-5-methoxymethoxy-pent-2-ene 
• 116382-00-4 ((3aS,6S,8aS)-8-Methyl-2,3,4,5,6,8a-hexahydro-1H-3a,6-methano-azulen-3-yl)-methanol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 116382-02-6 Toluene-4-sulfonic acid (3R,3aS,6S,7R,8R,8aS)-7-hydroxy-8-methyl-octahydro-3a,6-methano-azulen-3-ylmethyl ester 

Relevant academic research and scientific papers

SYNTHESIS OF VINYLCYCLOPROPANES VIA PALLADIUM-CATALYZED COUPLING OF CYCLOPROPYLZINC HALIDES WITH VINYL IODIDES. TOTAL SYNTHESES OF (+/-)-PREZIZANOL AND (+/-)-PREZIZAENE

Palladium(0)-catalyzed coupling of cyclopropylzinc halides, readily prepared from the corresponding cyclopropyl(tri-n-butyl)stannanes, with vinyl iodides provides good yields of functionalized vinylcyclopropanes.The coupling reaction is used as a key step in total syntheses of the sesquiterpenoids (+/-)-prezizanol and (+/-)-prezizaene.