116391-14-1

Basic information

• Product Name: methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2,3,4-tri-O-acetyl-α-D-rhamnopyranosyl)-α-D-glucopyranoside
• Synonyms: methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2,3,4-tri-O-acetyl-α-D-rhamnopyranosyl)-α-D-glucopyranoside
• CAS NO: 116391-14-1
• Molecular Weight: 644.673
• Mol File: 116391-14-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2,3,4-tri-O-acetyl-α-D-rhamnopyranosyl)-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2,3,4-tri-O-acetyl-α-D-rhamnopyranosyl)-α-D-glucopyranoside(116391-14-1)
• EPA Substance Registry System: methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2,3,4-tri-O-acetyl-α-D-rhamnopyranosyl)-α-D-glucopyranoside(116391-14-1)

Safety Data

• Hazardous Substances Data: 116391-14-1(Hazardous Substances Data)

Upstream product

• 14227-85-1 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl bromide 
• 15038-71-8 methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 127501-41-1 ethyl 2,3,4-tri-O-acetyl-1-thio-β-L-fucopyranoside 
• 76375-66-1 methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 3162-96-7 methyl 4,6-O-benzylidene-β-D-galactopyranoside 
• 15038-71-8 2-benzyl,3-hydroxy,4,6-benzylidene acetal-β-methyl galactopyranose 
• 5158-64-5 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl bromide 

Relevant articles and documents

Synthesis and Nuclear Magnetic Resonance Studies od some L-Fucosyl-containing Disaccharides

Eleven disaccharides containing an L-fucosyl group have been synthesized and their 1H and 13C NMR spectra assigned.HSEA analysis has indicated which inter-residue atomic interactions are present in the disaccharides, some of which could be correlated with observed glycosylation shifts.The results give further knowledge about glycosylation shifts, valuable for the interpretation of NMR spectra of larger saccharides.

N.M.R. AND CONFORMATIONAL STUDIES ON SOME 1,3-LINKED DISACCHARIDES

(13)C (1)H N.m.r. data have been obtained from 10 methyl 6-deoxyhexosylhexosides in which the 6-deoxysugar is the L- or D-enantiomer of fucose or rhamnose.A large variation in the magnitude of displacement shifts of signals for α- and β-carbons is observe