116415-18-0Relevant articles and documents
PALLADIUM-CATALYZED ACYLATION OF ACTIVATED ALKENES WITH BRIDGEHEAD ACID CHLORIDES
Hori, Kimihiko,Ando, Masatomo,Takaishi, Naotake,Inamoto, Yoshiaki
, p. 5883 - 5886 (2007/10/02)
Bridgehead acid chlorides 1a and 1b react with activated alkenes 2 in the presence of a catalytic amount of palladium and 1 equiv of a tertiary amine.The reaction proceeds regio- and stereoselectively at the terminal carbon atoms to yield acylated alkenes 3 with E-configuration.