116451-06-0Relevant academic research and scientific papers
Simple and highly efficient synthesis of oxaziridines by tetrabutylammonium Oxone
Mohajer, Daryoush,Iranpoor, Nasser,Rezaeifard, Abdolreza
, p. 631 - 634 (2004)
Oxygenation of various aldimines with tetrabutylammonium monoperoxysulfate produced the corresponding E- or a mixture of E- and Z-oxaziridines with very high yields (≥90%) and good to excellent selectivities (75-100%) within 20min to 10h in CH3CN at room temperature (~25°C). The E/Z isomer ratio critically depends on the stereo-electronic nature of the substituents in the oxaziridines, solvent, and the presence of Lewis acids and bases.
