116454-18-3

Upstream product

• 100-44-7 benzyl chloride 
• 91-09-8 methyl β-L-arabinopyranoside 

Downstream Products

• 1092684-39-3 (2S,3S,4R)-2-(hexacosanamido)-1-O-(2,3,4-tri-O-benzyl-β-L-arabinopyranosyl)octadecane-1,3,4-triol 
• 18039-26-4 2,3,4-tri-O-benzyloxy-L-arabinopyranose 
• 1093738-70-5 1-O-acetyl 2,3,4-tri-O-benzyl-α,β-L-arabinopyranose 

Relevant academic research and scientific papers

Benzylation of sugar polyols by means of the PTC method

Studies on benzylation of hydrophilic carbohydrate derivatives with benzyl chloride, using a phase-transfer technique, have led to the conclusion that alkylation of a substrate can be greatly facilitated by the introduction of a "co-catalyst" (e.g. a tertiary alcohol) and/or a co-solvent (e.g.DMSO) to the reaction mixture.Efficient procedures for benzylation of sugar derivatives having three to eight hydroxyl groups per molecule, in two-phase system employing an almost stoichiometric amount of the alkylating agent, are presented.