116490-97-2Relevant academic research and scientific papers
DOUBLE ASYMMETRIC INDUCTION IN THE OSMYLATION OF γ-ALKOXY-α,β-UNSATURATED ESTERS
Annunziata, Rita,Cinquini, Mauro,Cozzi, Franco,Raimondi, Laura
, p. 6897 - 6902 (2007/10/02)
OsO4 promoted cis-dihydroxylation of enantiomerically pure (E)-α,β-unsaturated esters derived from alkoxyaldehydes occurs with noticeable levels (up to>=45:1) of stereoselection when carried out in the presence of alkaloid derived ligands.Matching and mis
CATALYTIC OSMYLATION OF ELECTRON POOR ALLYLIC ALCOHOLS AND ETHERS. A SYNTHETIC APPROACH TO BRANCHED CHAIN SUGARS
Bernardi, Anna,Cardani, Silvia,Scolastico, Carlo,Villa, Roberto
, p. 491 - 502 (2007/10/02)
The catalytic osmylation of electron-poor allylic ethers and alcohols was studied.In the case of γ-alkoxy E-enoates reaction selectivity was found to range from 2:1 to 8:1 in favor of the arabino (2,3-syn - 3,4-anti) product, regardless of the double bond
