116491-87-3Relevant academic research and scientific papers
Dyotropic Rearrangement of Cycloalkyl β-Lactones. Formation of Spiro vs Fused Butyrolactones as a Function of Ring Size
Black, Howard T.,DuBay, William J.,Tully, Paul S.
, p. 5922 - 5927 (2007/10/02)
Trans 3-substituted-4-cycloalkyl β-lactones 4 and 8 have been prepared via the condensation of appropriately substituted acetic acid dianions 1 with cyclohexane- or cyclopentanecarboxaldehyde to afford the corresponding diastereomerically pure β-hydroxy a
LACTONE SYNTHESIS VIA DYOTROPIC REARRANGEMENT. STEREOSPECIFIC CONSTRUCTION OF FUSED BUTYROLACTONES WITH THREE CONTIGUOUS ASYMMETRIC CENTERS
Black, T. Howard,DuBay, William J.
, p. 1747 - 1750 (2007/10/02)
Substituted trans-fused cyclohexano butyrolactones are accessible via dyotropic rearrangement of β-lactones, wherein all three adjacent chiral centers are simultaneously fixed.
