116525-10-1Relevant articles and documents
Oligosaccharides Self-Assemble and Show Intrinsic Optical Properties
Yu, Yang,Gim, Soeun,Kim, Dongyoon,Arnon, Zohar A.,Gazit, Ehud,Seeberger, Peter H.,Delbianco, Martina
, p. 4833 - 4838 (2019)
Self-assembling peptides and oligonucleotides have given rise to synthetic materials with several applications in nanotechnology. Aggregation of synthetic oligosaccharides into well-defined architectures has not been reported even though natural polysacch
Dehydrative glycosylation by diethylaminosulfur trifluoride (DAST) - tin(II) trifluoromethanesulfonate-tetrabutylammonium perchlorate - triethylamine system
Hirooka, Motoko,Koto, Shinkiti
, p. 2893 - 2902 (2007/10/03)
Dehydrative glycosylation using 2,3,4,6-tetra-O-benzyl-D-glucopyranose was carried out by the use of a condensing reagent system composed of diethylaminosulfur trifluoride (DAST), tin(II) triflate, tetrabutylammonium perchlorate, and triethylamine. Using this system, two tetrasaccharides, O- a-D-glucopyranosyl-(1→4)-O-α-D-glucopyranosyl-(1→3)-Oα-D-glucopyranosyl- (1→4)-D-glucopyranose and O-a-D-glucopyranosyl-(1→3)-O-α-D- glucopyranosyl-(1→4)-O-α-D-glucopyranosyl-(1→4)-D-glucopyranose, were synthesized.
SYNTHESIS OF 6-O-α-D-GLUCOPYRANOSYLCYCLOMALTOHEPTAOSE
Fuegedi, Peter,Nanasi, Pal,Szejtli, Jozsef
, p. 173 - 182 (2007/10/02)
(2,3-Di-O-acetyl)hexakis(2,3,6-tri-O-acetyl)cyclomaltoheptaose was prepared by reaction of cyclomaltoheptaose with tert-butyldimethylsilyl chloride in pyridine followed by acetylation and desilylation.Glycosylation with 2,3,4,6-tetra-O-benzoyl-1-O-trichloroacetimidoyl-α-D-glucopyranose, using trifluoromethanesulfonic acid as catalyst, and removal of the protecting groups from the product then afforded the title compound.