116525-41-8Relevant academic research and scientific papers
PHENYL-α,α,ω-TRIHYDROPOLYFLUOROALKYLIODONIUM FLUOROBORATES
Mironova, A. A.,Soloshonok, I. V.,Maletina, I. I.,Orda, V. V.,Yagupol'skii, L. M.
, p. 530 - 535 (2007/10/02)
The reaction of difluoroiodo-α,α,ω-trihydropolyfluoroalkanes (I) with boron trifluoride and benzene gave phenyl-α,α,ω-trihydropolyfluoroalkyliodonium fluoroborates (II).It was established that the polyfluoroalkyl radical adds at the sulfur atom in reaction with p-chlorothiophenol, the N-polyfluoroalkylation product is formed with aniline, pyridine is polyfluoroalkylated at the nitrogen atom with the formnation of a quaternary salt, and a mixture of products from polyfluoroalkylation at the nitrogen atom of the dimethylamino group and at the para position of the benzene ring is formed with dimethylaniline.
