116538-60-4Relevant articles and documents
Synthetic Application of Tris(methylthio)methyl Salts. An Efficient Route to Trithioorthocarboxylic Esters from Strongly Activated Aromatic and Heteroaromatic Systems
Barbero, Margherita,Cadamuro, Silvano,Degani, Iacopo,Fochi, Rita,Gatti, Antonella,Regondi, Valeria
, p. 22 - 25 (2007/10/02)
Nine trithioorthocarboxylic esters were synthesized by reaction of tris(methylthio)methyl methyl sulfate or tetrafluoroborate with electron-rich aromatic and heteroaromatic compounds, i.e.N,N-dialkylarylamines, pyrroles, and indoles.The new procedure is simple and offers the following advantages: easy preparation of reagents; mild reaction condition; possibility to introduce two tris(methylthio)methyl groups into the same ring, good to excellent yields.