116545-01-8Relevant academic research and scientific papers
Highly efficient two-step synthesis of C-sp3-centered geminal diiodides
Cloarec, Jean-Manuel,Charette, Andre B.
, p. 4731 - 4734 (2004)
(Chemical Equation Presented) Trisubstituted gem-diiodoalkenes of functionalized chains are efficiently reduced to the corresponding terminal geminal diiodides in high yields upon treatment with the diazene precursor, diethyl 4-(hydrazinosulfonyl)-benzyl phosphonate.
Z-1-VINYLIODIDE DURCH WITTIG-REAKTION
Bestmann, Hans Juergen,Rippel, Hans Christoph,Dostalek, Roman
, p. 5261 - 5262 (2007/10/02)
A wide spectrum of Z-1-iodo-alkenes is available by Wittig reaction of iodomethylenetrimethylphosphorane with aldehydes.The formation of 1,1-diiodo-1-alkenes as byproducts is explained.
Copper(I) Iodide-Assisted Halogen Exchange at Vinylic Positions. Conversion of Vinyl Vinylene, and Vinylidene Bromides to the Corresponding Iodo Analogs
Suzuki, Hitomi,Aihara, Mie,Yamamoto, Hidetoshi,Takamato, Yuuko,Ogawa, Takuji
, p. 236 - 238 (2007/10/02)
The title bromo olefins undergo the copper(I) iodide-mediated exchange with iodide ion in hot hexamethylenephosphoric triamide to give the corresponding iodo analogs in moderate to good yield.
