116557-48-3

Basic information

• Product Name: 2-hydroxy-9,10-dihydroanthracene
• Synonyms: 2-hydroxy-9,10-dihydroanthracene
• CAS NO: 116557-48-3
• Molecular Weight: 196.249
• Mol File: 116557-48-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-hydroxy-9,10-dihydroanthracene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-hydroxy-9,10-dihydroanthracene(116557-48-3)
• EPA Substance Registry System: 2-hydroxy-9,10-dihydroanthracene(116557-48-3)

Safety Data

• Hazardous Substances Data: 116557-48-3(Hazardous Substances Data)

Upstream product

• 613-31-0 9,10-dihydroanthracene 

Downstream Products

• 1079-71-6 1,2,3,4,5,6,7,8-octahydroanthracene 
• 2141-42-6 1,2,3,4-tetrahydroanthracene 

Relevant articles and documents

Insight into the chemoselective aromatic: Vs. side-chain hydroxylation of alkylaromatics with H2O2catalyzed by a non-heme imine-based iron complex

The oxidation of a series of alkylaromatic compounds with H2O2 catalyzed by an imine-based non-heme iron complex prepared in situ by reaction of 2-picolylaldehyde, 2-picolylamine, and Fe(OTf)2 in a 2?:?2?:?1 ratio leads to a marked chemoselectivity for aromatic ring hydroxylation over side-chain oxidation. This selectivity is herein investigated in detail. Side-chain/ring oxygenated product ratio was found to increase upon decreasing the bond dissociation energy (BDE) of the benzylic C-H bond in line with expectation. Evidence for competitive reactions leading either to aromatic hydroxylation via electrophilic aromatic substitution or side-chain oxidation via benzylic hydrogen atom abstraction, promoted by a metal-based oxidant, has been provided by kinetic isotope effect analysis. This journal is