1165950-62-8Relevant academic research and scientific papers
First enantioselective total synthesis of (+)-(R)-pinnatolide using an asymmetric domino allylation reaction
Tietze, Lutz F.,Wolfram, Thomas,Holstein, Julian J.,Dittrich, Birger
, p. 4035 - 4037 (2012)
An efficient total synthesis of (+)-(R)-Pinnatolide is described. As a key step an asymmetric multicomponent domino allylation reaction of methyl levulinate is used to form the quaternary stereogenic center in a highly selective way.
Asymmetrie allylation of methyl ketones by using chiral phenyl carbinols
Tietze, Lutz F.,Kinzel, Tom,Wolfram, Thomas
experimental part, p. 6199 - 6210 (2010/03/01)
Novel chiral auxiliaries for the stereoselective allylation of aliphatic methyl ketones with allyltrimethylsilane and their use in the synthesis of homoallylic ethers are described. In a multicomponent domino process catalyzed by trifluoromethanesulfonic
