116596-29-3 Usage
General Description
1,1,5,5-tetranitro-(4)peristylane is a highly explosive chemical compound with the molecular formula C22H16N8O12. It is classified as a nitro compound and is known for its high sensitivity to shock, friction, and heat, making it extremely dangerous to handle. Due to its explosive nature, 1,1,5,5-tetranitro-(4)peristylane is primarily used in the production of high-energy materials and explosives. Its structure consists of a peristylane core surrounded by four nitro functional groups, which contribute to its powerful explosive properties. Due to the hazards associated with its handling and storage, strict safety measures and protocols must be followed when working with 1,1,5,5-tetranitro-(4)peristylane.
Check Digit Verification of cas no
The CAS Registry Mumber 116596-29-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,6,5,9 and 6 respectively; the second part has 2 digits, 2 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 116596-29:
(8*1)+(7*1)+(6*6)+(5*5)+(4*9)+(3*6)+(2*2)+(1*9)=143
143 % 10 = 3
So 116596-29-3 is a valid CAS Registry Number.
InChI:InChI=1/C12H12N4O8/c17-13(18)11(14(19)20)3-1-4-8-7(3)9-5(11)2-6(10(8)9)12(4,15(21)22)16(23)24/h3-10H,1-2H2
116596-29-3Relevant articles and documents
Synthesis of Nitro Derivatives of Peristylane Having High-Density Characteristic
Waykole, Liladhar M.,Shen, Chien-Chang,Paquette, Leo A.
, p. 4969 - 4972 (2007/10/02)
Reduction of the dioxime of peristylane-2,6-dione (8) with sodium cyanoborohydride delivered the bis(hydroxylamine) 9, which was directly condensed with N-benzylidenebenzenesulfonamide and benzaldehyde to give the bis(nitrone) 10.Ozonolysis of 10 gave rise to endo,endo-2,6-dinitroperistylane (6).In a separate sequence, 8 was oxidized with 100percent nitric acid in the presence of ammonium nitrate.The resulting dinitro ketone 11 was oximated and then oxidatively brominated.When sodium borohydride reduction of 14 was uncovered to proceed with transannular CC bond formation, the dinitro oxime 12 was instead oxidized as above.The reaction afforded the targeted 2,2,6,6-tetranitroperistylane (7).Density measurements performed on 6, 7, 11, and 13 indicate that the presence of one geminal pair of nitro groups increases crystal packing efficiency steeply.However, the presence of a second pair of nitro groups transannular to the first has little more impact than positioning of a ketone carbonyl or lactone bridge at that site.
