116669-50-2

Basic information

• Product Name: Benzene, (1,4-dimethyl-1,3-pentadienyl)-, (E)-
• CAS NO: 116669-50-2
• Molecular Formula: C13H16
• Molecular Weight: 172.27
• Mol File: 116669-50-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, (1,4-dimethyl-1,3-pentadienyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1,4-dimethyl-1,3-pentadienyl)-, (E)-(116669-50-2)
• EPA Substance Registry System: Benzene, (1,4-dimethyl-1,3-pentadienyl)-, (E)-(116669-50-2)

Safety Data

• Hazardous Substances Data: 116669-50-2(Hazardous Substances Data)

Upstream product

• 103392-14-9 5-methyl-2-phenyl-hexan-3-one 
• 1315460-76-4 C₁₄H₁₇F₃O₃S 
• 122444-76-2 5-Methyl-2-phenyl-1,3,4-hexatriene 
• 617-86-7 triethylsilane 
• 84313-25-7 (Z)-5-Methyl-2-phenyl-1,3-hexadien 

Relevant articles and documents

Palladium-catalyzed elimination/isomerization of enol triflates into 1,3-dienes

Dying to be Dienes: Substituted 1,3-dienes were synthesized by the title reaction (see scheme; Tf=trifluoromethanesulfonyl). Preliminary studies support a mechanistically distinct pathway that involves an initial β-hydride elimination from a cationic vinyl palladium(II) intermediate, a subsequent regiospecific hydropalladation of the corresponding allene intermediate, and a final β-hydride elimination. Copyright

Facial Selectivities and Rate Effects in the Thermal Dimerization of Arylated 1,3-Dienes. 1,5-H Shift versus Dimerization of (Z)-1,3-Dienes

For the thermal dimerization of the dienes 1 and 4 a parallel increase in facial selectivity and reaction rate is observed on going from the (E)-alkyl-aryl dienes 1h-m and the (Z)-dienes 4a, b to the (E)-aryl-aryl dienes 1a-f.This phenomenon is inte