116696-85-6

Basic information

• Product Name: (2S)-2-BOC-AMINO-3-PHENYLSULFONYL-1-(2-TETRAHYDROPYRANYLOXY)PROPANE, 97
• Synonyms: (2S)-2-BOC-AMINO-3-PHENYLSULFONYL-1-(2-TETRAHYDROPYRANYLOXY)PROPANE, 97;(2S)-2-BOC-AMINO-3-PHENYLSULPHONYL-1-(2-TETRAHYDROPYRANYLOXY)PROPANE;(2S)-2-BOC-AMINO-3-PHENYLSULFONYL-1-(2-TETRAHYDROPYRANYLOXY)PROPANE 97%
• CAS NO: 116696-85-6
• Molecular Formula: C₁₉H₂₉NO₆S
• Molecular Weight: 399.51
• Mol File: 116696-85-6.mol
• Article Data: 1

Chemical Properties

• Melting Point: 100-104°C
• Boiling Point: 590.7°Cat760mmHg
• Flash Point: 311.1°C
• Appearance: /
• Density: 1.1966 (rough estimate)
• Vapor Pressure: 6.27E-14mmHg at 25°C
• Refractive Index: 1.5800 (estimate)
• CAS DataBase Reference: (2S)-2-BOC-AMINO-3-PHENYLSULFONYL-1-(2-TETRAHYDROPYRANYLOXY)PROPANE, 97(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-2-BOC-AMINO-3-PHENYLSULFONYL-1-(2-TETRAHYDROPYRANYLOXY)PROPANE, 97(116696-85-6)
• EPA Substance Registry System: (2S)-2-BOC-AMINO-3-PHENYLSULFONYL-1-(2-TETRAHYDROPYRANYLOXY)PROPANE, 97(116696-85-6)

Safety Data

• Hazardous Substances Data: 116696-85-6(Hazardous Substances Data)

Usage

Chemical Properties

WHITE FLUFFY FINE CRYSTALLINE POWDER

InChI:InChI=1/C19H29NO6S/c1-19(2,3)26-18(21)20-15(13-25-17-11-7-8-12-24-17)14-27(22,23)16-9-5-4-6-10-16/h4-6,9-10,15,17H,7-8,11-14H2,1-3H3,(H,20,21)/t15-,17+/m0/s1

Upstream product

• 2766-43-0 N-tert-butyloxycarbonyl-L-serine methyl ester 
• 116611-49-5 ((S)-1-Hydroxymethyl-2-phenylsulfanyl-ethyl)-carbamic acid tert-butyl ester 
• 116611-47-3 Toluene-4-sulfonic acid (S)-2-tert-butoxycarbonylamino-3-(tetrahydro-pyran-2-yloxy)-propyl ester 
• 116611-48-4 [(S)-2-Phenylsulfanyl-1-(tetrahydro-pyran-2-yloxymethyl)-ethyl]-carbamic acid tert-butyl ester 
• 116611-63-3 methyl N-(tert-butoxycarbonyl)-O-(tetrahydro-2H-pyran-2-yl)-L-serinate 
• 116611-46-2 tert-butyl [(2R)-1-hydroxy-3-(tetrahydro-2H-pyran-2-yloxy)propan-2-yl]carbamate 
• 110-87-2 3,4-dihydro-2H-pyran 
• 116611-50-8 ((S)-2-Benzenesulfonyl-1-hydroxymethyl-ethyl)-carbamic acid tert-butyl ester 

Downstream Products

• 116611-53-1 [(S)-2-Benzenesulfonyl-1-(tetrahydro-pyran-2-yloxymethyl)-pentyl]-carbamic acid tert-butyl ester 
• 125700-55-2 [(E)-(S)-2-Benzenesulfonyl-1-(tetrahydro-pyran-2-yloxymethyl)-but-2-enyl]-carbamic acid tert-butyl ester 
• 116611-60-0 ((S)-2-Benzenesulfonyl-1-hydroxymethyl-3-phenyl-propyl)-carbamic acid tert-butyl ester 
• 116611-62-2 ((S)-2-Benzenesulfonyl-1-hydroxymethyl-pentyl)-carbamic acid tert-butyl ester 
• 116611-61-1 ((S)-2-Benzenesulfonyl-1-hydroxymethyl-butyl)-carbamic acid tert-butyl ester 
• 116611-56-4 tert-butyl (R)-(1-hydroxy-4-phenylbutan-2-yl)carbamate 
• 55674-63-0 (R)-2-(N-t-butoxycarbonylamino)hexanoic acid 
• 57521-85-4 N-tert-butoxycarbonyl-D-norvaline 
• 116640-17-6 tert-butyl (R)-(1-hydroxyhexan-2-yl)carbamate 
• 116611-55-3 (R)-tert-butyl (1-hydroxypentan-2-yl)carbamate 
• 100564-78-1 (2R)-(tert-butoxycarbonylamino)-4-phenylbutanoic acid 
• 116611-51-9 [(S)-2-Benzenesulfonyl-3-phenyl-1-(tetrahydro-pyran-2-yloxymethyl)-propyl]-carbamic acid tert-butyl ester 
• 125700-54-1 Acetic acid (S)-2-benzenesulfonyl-3-tert-butoxycarbonylamino-1-methyl-4-(tetrahydro-pyran-2-yloxy)-butyl ester 
• 116611-52-0 [(S)-2-Benzenesulfonyl-1-(tetrahydro-pyran-2-yloxymethyl)-butyl]-carbamic acid tert-butyl ester 

Relevant articles and documents

A NOVEL APPROACH TO THE SYNTHESIS OF OPTICALLY PURE NON PROTEIN α-AMINO ACIDS IN BOTH L AND D CONFIGURATIONS FROM L-SERINE

Efficient syntheses of (2R)-2-Boc-amino-3-phenylsulfonyl-1-propanol 3 and its enantiomer 9 from L-serine are described.The potential of these compounds in a novel general method for the synthesis of optically pure non protein α-amino acids in both the L and D configurations is exemplified by the preparation of N-Boc-L-and D-homophenylalanine,-norvaline and -norleucine.