116697-07-5Relevant academic research and scientific papers
HIGHLY STEREOSELECTIVE REFORMATSKY REACTIONS OF 3-(2-BROMOPROPIONYL)-2-OXAZOLIDONE DERIVATIVES WITH VARIOUS ALDEHYDES
Ito, Yoshio,Terashima, Shiro
, p. 2821 - 2834 (1991)
The Reformatsky reactions of 3-(2-bromopropionyl)-2-oxazolidone derivatives with various aldehydes were investigated to elucidate the effects of substituents in the 2-oxazolidone moieties on their diastereoselectivities.The highest 2,3-syn-diastereoselect
A HIGHLY STEREOSELECTIVE SYNTHESIS OF ALDOLS EMPLOYING THE REFORMATSKY REACTION OF 3-(2-BROMOPROPIONYL)-2-OXAZOLIDONE DERIVATIVES WITH VARIOUS ALDEHYDES
Ito, Yoshio,Terashima, Shiro
, p. 6629 - 6632 (2007/10/02)
The title reactions of sterically crowded 2-oxazolidone derivatives with achiral aldehydes in the presence of zinc dust were found to give various 2,3-syn-aldols as major products (at most, 2,3-syn:2,3-anti=98:2).While a 2,3-syn-3,4-syn-aldol could be sim
