116749-03-2Relevant academic research and scientific papers
Lanthanide- and DMSO-Induced Ring Opening of 2-Iminooxetanes: Synthesis of β-Lactams and β-Keto Amides
Barbaro, Gaetano,Battaglia, Arturo,Giorgianni, Patrizia
, p. 1020 - 1025 (2007/10/02)
2-Iminooxetanes (1), generated by lanthanide-catalyzed heterocycloaddition of aldehydes to ketene imines, are versatile synthons for β-lactams (2) and for β-keto amides (3).Conversion of 1 into 2 and 3 can be accomplished by either lanthanide-induced or o
2-Iminooxetane Chemistry. 2. General Synthesis from Ketene Imine-Aldehyde Cycloadditions
Barbaro, Gaetano,Battaglia, Arturo,Giorgianni, Patrizia
, p. 5501 - 5506 (2007/10/02)
2-Iminooxetanes, versatile synthons of highly functionalized γ-amino alcohols, β-keto amides, β-hydroxy amides, and β-lactams, are synthesized by regiospecific 2 + 2 cycloadditions of aldehydes to ketene imines in the presence of lanthanide shift reagents
