1167993-22-7Relevant academic research and scientific papers
A desymmetrization approach toward highly oxygenated cis-decalins
Gromov, Alexey,Enev, Valentin,Mulzer, Johann
supporting information; experimental part, p. 2884 - 2886 (2009/12/24)
The cis-decalin core 2 of the antibiotic branimycin has been prepared by desymmetrization of diepoxynaphthalene 4. The key steps involve two successive SN' opening of the oxa-bridges. An improved procedure for the synthesis of 4 Is also described.
