1168-15-6

Basic information

• Product Name: (2E)-1-(1-oxidoquinolin-4-yl)-2-(1-oxoquinolinium-4(1H)-ylidene)hydrazinolate
• CAS NO: 1168-15-6
• Molecular Formula: C₁₈H₁₂N₄O₃
• Molecular Weight: 332.3129
• Mol File: 1168-15-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (2E)-1-(1-oxidoquinolin-4-yl)-2-(1-oxoquinolinium-4(1H)-ylidene)hydrazinolate(CAS DataBase Reference)
• NIST Chemistry Reference: (2E)-1-(1-oxidoquinolin-4-yl)-2-(1-oxoquinolinium-4(1H)-ylidene)hydrazinolate(1168-15-6)
• EPA Substance Registry System: (2E)-1-(1-oxidoquinolin-4-yl)-2-(1-oxoquinolinium-4(1H)-ylidene)hydrazinolate(1168-15-6)

Safety Data

• Hazardous Substances Data: 1168-15-6(Hazardous Substances Data)

Usage

General Description

The chemical "(2E)-1-(1-oxidoquinolin-4-yl)-2-(1-oxoquinolinium-4(1H)-ylidene)hydrazinolate" is a complex compound that contains quinoline and hydrazine moieties. It is composed of a hydrazine group attached to a quinolinium ring, resulting in a unique molecular structure. (2E)-1-(1-oxidoquinolin-4-yl)-2-(1-oxoquinolinium-4(1H)-ylidene)hydrazinolate has potential applications in various fields, including pharmaceuticals, materials science, and organic synthesis. Its specific properties and reactivity make it a subject of interest for researchers and scientists studying novel chemical compounds and their potential uses. Further research is needed to explore the full potential and applications of this complex chemical.

Upstream product

• 18061-48-8 1-acetoxy-4-(acetoxyimino)-1,4-dihydroquinoline 
• 2669-36-5 4-quinolyl azide N-oxide 
• 4637-59-6 4-Chloroquinoline N-oxide 
• 4637-56-3 4-(hydroxyamino)quinoline N-oxide 

Relevant articles and documents

4-Azidoquinoline N-oxide: Synthesis and photolysis

In photolysis of 4-azidoquinoline N-oxide azoxy compound was isolated as the final reaction product. This result may be ascribed to the dimerization of the intermediate nitrene to azo compound followed by oxidation of the latter with air oxygen. The initially arising nitrene is stabilized by resonance conjugation involving the aromatic system and the N-oxide group. The rate constants of 4-azidoquinoline N-oxide photolysis were measured in various solvents and the values of spin density and bond lengths in the formed nitrene were calculated.

Concerning Model Metabolites of the Carcinogen 4-Nitroquinoline 1-Oxide. Reactivity of 1-Acetoxy-4-(hydroxyimino)-1,4-dihydroquinoline

1-Acetoxy-4-(hydroxyimino)-1,4-dihydroquinoline is obtained by hydrolysis of 1-acetoxy-4-(acetoxyimino)-1,4-dihydroquinoline under strongly acidic conditions.At pH 1 the monoacetate is protonated and on hydrolysis affords only 1-hydroxy-4-(hydroxyimino)-1,4-dihydroquinoline.Above pH 1 on hydrolysis the monoacetate affords a complex product mixture including 4-(hydroxyamino)quinoline and 4-nitrosoquinoline.Comparison of the above behavior of 1-acetoxy-4-(hydroxyamino)-1,4-dihydroquinoline with that of 1-hydroxy-4-(acetoxyimino)-1,4-dihydroquinoline at a neutral pH suggests that the former type of ester is less likely to be important in those steps initiating oncogenesis.In contrast the latter type of monoester or diesters corresponding to 1-acetoxy-4-(acetoxyimino)-1,4-dihydroquinoline by their ability to generate nitrenium ion intermediates and undergo attack by nucleophiles at the 3-position are likely intermediates in the process of oncogenesis.Further aspects of their likely biological role are discussed.

Polarization of heterocyclic rings with aromatic character. CXVIII. 4-Hydroxyaminoquinoline-N-oxide.

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