1169876-08-7Relevant academic research and scientific papers
SmI2-mediated dialdehyde cyclization cascades
Helm, Matthew D.,Sucunza, David,Silva, Madeleine Da,Helliwell, Madeleine,Procter, David J.
scheme or table, p. 3224 - 3226 (2009/08/17)
Dialdehydes undergo sequenced SmI2-mediated cyclization cascades generating four contiguous stereocenters with high diastereocontrol.
SmI2-mediated dialdehyde 'radical then aldol' cyclization cascades: a feasibility study
Helm, Matthew D.,Da Silva, Madeleine,Sucunza, David,Helliwell, Madeleine,Procter, David J.
experimental part, p. 10816 - 10829 (2010/02/28)
Dialdehydes undergo 'radical then aldol' cyclization cascades upon treatment with SmI2, generating four contiguous stereocenters with high diastereocontrol. The scope of the process has been explored and the cascade has been extended to also in
