117009-29-7Relevant academic research and scientific papers
Vinyl selenones: Annulation agents for the synthesis of six-membered benzo-1,4-heterocyclic compounds
Bagnoli, Luana,Casini, Sara,Marini, Francesca,Santi, Claudio,Testaferri, Lorenzo
, p. 481 - 486 (2013/02/23)
A novel and general approach to six-membered bicyclic benzo fused 1,4-heterocycles is described. The addition-cyclization cascade of benzo 1,2-diols, 1,2-thiols and 2-(benzylamino)phenols with stable and easily available vinyl selenones affords differently substituted 2,3-dihydro-1,4- benzodioxines, benzodithiines and 3,4-dihydro-2H-1,4-benzoxazines in good yields. The same procedure has been extended to the synthesis of 1,2,3,4-tetrahydroquinoxalines. All of these heterocycles are present in a variety of biologically active compounds.
