117015-27-7Relevant academic research and scientific papers
A Synthesis of (-)-12,15-Epoxylabda-8(17),12,14-trien-16-yl Acetate and (-)-Pumiloxide
Cambie, Richard C.,Moratti, Stephen C.,Rutledge, Peter S.,Weston, Roderick J.,Woodgate, Paul D.
, p. 1151 - 1162 (2007/10/02)
Sclareol (7) and manoyl oxide (8) have each been converted into the (-)-enantiomers of the naturally occurring diterpenoids 12,15-epoxylabda-8(17),12,14-trien-16-yl acetate (2) and pumiloxide (1).
Functionalisation of Saturated Hydrocarbons. Part IX. Oxidation of Cedrol, β- and γ-Eudesmol, Sclareol, Manoyl Oxide, 1,9-Dideoxyforskolin, Methyl trans-Dihydrojasmonate, and Tetrahydrolinalool by the 'Gif System'
Barton, Derek H. R.,Beloeil, Jean-Claude,Billion, Annick,Boivin, Jean,Lallemand, Jean-Yves,et al.
, p. 2187 - 2200 (2007/10/02)
The oxidation of cedrol (1), β- and γ-eudesmol (6 and 7, resp.), sclareol (14), manoyl oxide (15), 1,9-dideoxyforskolin (22) (+/-)-methyl trans-dihydrojasmonate (28), and tetrahydrolinalool (32), nearly all of natural terpenoid origin, by the 'Gif system' has afforded a number of novel products (3, 11, and 12, 16/17, 18/19, 26, 29-31, and ketones corresponding to 34-35, resp.).The structures of these compounds were established by spectroscopic techniques including 2D-NMR and, where appropriate, by comparison with authentic samples.
