Welcome to LookChem.com Sign In|Join Free

CAS

  • or

117111-19-0

The complex **(η2-2,2-dimethyl-1-methylenecyclopropane)bis(triphenylphosphine)nickel(0)** is a nickel(0) olefin complex formed by the coordination of 2,2-dimethyl-1-methylenecyclopropane to a nickel center stabilized by two triphenylphosphine ligands. It is part of a series of novel nickel(0) complexes derived from methyl-substituted methylenecyclopropanes, demonstrating the ability of such strained cyclic olefins to bind to low-valent nickel in an η2-fashion. Other names for (η2-2,2-dimethyl-1-methylenecyclopropane)bis(triphenylphosphine)nickel may include **bis(triphenylphosphine)(2,2-dimethyl-1-methylenecyclopropane)nickel(0)** or variations emphasizing the η2-coordination mode. The complex highlights the reactivity of nickel(0) phosphine systems with strained alkenes, a feature relevant to catalytic applications.

117111-19-0 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 117111-19-0 Structure

  • Basic information

    1. Product Name: (η2-2,2-dimethyl-1-methylenecyclopropane)bis(triphenylphosphine)nickel
    2. Synonyms:
    3. CAS NO:117111-19-0
    4. Molecular Formula:
    5. Molecular Weight: 665.417
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 117111-19-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (η2-2,2-dimethyl-1-methylenecyclopropane)bis(triphenylphosphine)nickel(CAS DataBase Reference)
    10. NIST Chemistry Reference: (η2-2,2-dimethyl-1-methylenecyclopropane)bis(triphenylphosphine)nickel(117111-19-0)
    11. EPA Substance Registry System: (η2-2,2-dimethyl-1-methylenecyclopropane)bis(triphenylphosphine)nickel(117111-19-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 117111-19-0(Hazardous Substances Data)

117111-19-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 117111-19-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,7,1,1 and 1 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 117111-19:
(8*1)+(7*1)+(6*7)+(5*1)+(4*1)+(3*1)+(2*1)+(1*9)=80
80 % 10 = 0
So 117111-19-0 is a valid CAS Registry Number.

117111-19-0Relevant articles and documents

Novel olefin nickel(0) complexes of the methyl derivatives of methylenecyclopropane and cyclopropene

Isaeva, L. S.,Peganova, T. A.,Petrovskii, P. V.,Kravtsov, D. N.

, p. 141 - 148 (1989)

The interaction of phosphine nickel complexes Ni(PPh3)3 and Ni(PPh3)2(ε2-C2H4) with methyl derivatives of methylenecyclopropane and cyclopropene has been studied.The novel olefin complexes: (ε2-2,2-dimethyl-1-metylenecyclopropane)bis

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 117111-19-0