1171235-06-5Relevant academic research and scientific papers
Reactivity of dearomatised furans synthesised via the decarboxylative Claisen rearrangement
Camp, Jason E.,Craig, Donald
, p. 3503 - 3508 (2009)
The decarboxylative Claisen rearrangement (dCr) reaction of 1-(furan-2-yl)ethyl 2-tosylacetate afforded 2-ethylidene-3-(tosylmethyl)-2,3-dihydrofuran. Reaction of the dearomatised heterocycle with a variety of electrophiles gave addition products with excellent syn-diastereoselectivity. The furanol adducts were then utilised as functionalised scaffolds for a series of subsequent transformations.
