1171247-70-3

Basic information

• Product Name: BbtP=P(9-Anth)
• CAS NO: 1171247-70-3
• Molecular Weight: 863.633
• Mol File: 1171247-70-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: BbtP=P(9-Anth)(CAS DataBase Reference)
• NIST Chemistry Reference: BbtP=P(9-Anth)(1171247-70-3)
• EPA Substance Registry System: BbtP=P(9-Anth)(1171247-70-3)

Safety Data

• Hazardous Substances Data: 1171247-70-3(Hazardous Substances Data)

Upstream product

• 882693-31-4 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenylphosphine 
• 141982-25-4 (9-anthracenyl)dichlorophosphane 

Downstream Products

• 1171247-71-4 C₅₀H₈₆P₂Si₇ 
• 928-53-0 maleonitrile 
• 621110-78-9 BbtP=PBbt 
• 1206455-07-3 1,2-bis(9-anthryl)-3-{2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl}-triphosphirane 

Relevant articles and documents

Synthesis, structures, and reactivity of kinetically stabilized anthryldiphosphene derivatives

The first stable anthryldiphosphenes, 1 and 2, were synthesized by utilizing kinetic stabilization of 2,4,6- tris[bis(trimethylsilyl)methyl]phenyl (Tbt) and 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl] phenyl (Bbt) groups, and were characterized by spectroscopic and X-ray crystallographic analyses. The UVvisible spectroscopic data suggested the electronic communication between the anthryl moiety and the P=P unit. It was found that TbtP=P(9- Anth) (1a: 9-Anth = 9-anthryl) showed weak fluorescence in hexane solution. Furthermore, the reactivities of anthryldiphosphene 1 with a chromium complex, chalcogenation reagents, a diene, and electron-deficient olefins have been revealed.