117125-18-5Relevant articles and documents
Synthesis of 4-Vinylquinoline: Pyrolytic Rearrangement of the 4-(1-Hydroxyethyl)quinoline and Related Derivatives
Rodriguez, J. G.,Benito, Y.
, p. 819 - 821 (2007/10/02)
The synthesis of 4-vinylquinoline has been carried out by means of the Wittig reaction between 4-quinolinecarbaldehyde and the methyl triphenylphosphonium ylide in dimethyl sulphoxide in good yield.Dehydration of the 4-(1-hydroxyethyl)quinoline and their xanthate derivative, give equimolar amounts of 4-ethylquinoline and 4-acetylquinoline while small amounts of 4-vinylquinoline were found.Dehydrochlorination of 4-(1-chloroethyl)quinoline in ethanol-sodium hydroxide provides 4-ethyl-3-ethoxyquinoline in good yield, but 4-vinylquinoline is a minor reaction product.