117157-11-6Relevant articles and documents
Radical Reaction of Alkenylstannanes with S-Benzoyl Se-Phenyl Selenosulfide
Toru, Takeshi,Yamada, Yoshio,Maekawa, Eturo,Ueno, Yoshio
, p. 2205 - 2207 (1988)
Free radical reactions of allyltributylstannane or 2-butenyltributylstannane with S-benzoyl Se-phenyl selenosulfide (1) gave S-allyl benzenecarbothioate or a mixture of S-2-butenyl and S-1-methyl-2-propenyl benzenecarbothioates, respectively.The reaction of tributylvinylstannane with 1 gave an addition product, whereas the reaction of tributylstyrylstannane gave an addition-elimination product.
Reaction of Olefins with Se-Phenyl (Selenothioperoxy)benzoate: A New Anti-Markownikoff Benzeneselenenylation
Toru, Takeshi,Seko, Takuya,Maekawa, Eturo,Ueno, Yoshio
, p. 575 - 582 (2007/10/02)
A novel free radical addition of Se-phenyl (selenothioperoxy)benzoate (1) to a variety of olefins is described.The addition of selenosulphide (1) to terminal olefins proceeds regiospecifically to give the anti-Markownikoff benzeneselenenylated adducts.The