117174-24-0Relevant academic research and scientific papers
Regio- and Face-Selective 1,3-Dipolar Cycloadditions to Levoglucosenone
Blake, Alexander J.,Forsyth, Angus C.,Paton, Michael R.
, p. 440 - 442 (1988)
Benzonitrile oxide and C,N-diphenylnitrone undergo highly regio- and face-selective cycloaddition reactions with levoglucosenone; in each case the major product results from approach anti to the 1,6-bridge of levoglucosenone, the oxygen of the 1,3-dipole becoming attached to the β-carbon of the enone unit.
1,3-Dipolar Cycloaddition Reactions of Levoglucosenone
Blake, Alexander J.,Cook, Tracey A.,Forsyth, Angus C.,Gould, Robert O.,Paton, R. Michael
, p. 8053 - 8064 (2007/10/02)
The cycloaddition reactions of levoglucosenone with various 1,3-dipoles have been examined.Benzonitrile oxide underwent regiospecific and face-selective cycloaddition yielding isoxazoline 2a as the major product.D-Glyceraldehyde-derived nitrile oxide 6 wa
