117174-92-2Relevant academic research and scientific papers
STEREOSELECTIVE SYNTHESIS OF γ-HYDROXY-α-AMINO ACIDS via INTRAMOLECULAR AMIDOMERCURATION
Harding, Kenn E.,Marman, Thomas H.,Nam, Do-hyun
, p. 5605 - 5614 (2007/10/02)
A general method for the stereoselective conversion of homoallylic alcohols to erythro- or threo-γ-hydroxy-α-amino acids is described.The key step is the stereoselective mercuric ion-initiated cyclofunctionalization of acylaminomethyl ether derivatives of
SELECTIVITY IN THE AMINATION OF ALLYLIC ALCOHOLS via INTRAMOLECULAR AMIDOMERCURATION
Harding, Kenn E.,Hollingsworth, Donald R.
, p. 3789 - 3792 (2007/10/02)
Intramolecular amidomercuration reactions of acylaminomethyl derivatives of γ-substituted allylic alcohols were examined.The effect of oxygen substitution on the δ carbon and of the geometry of the double bond on the regiochemistry and stereochemistry of
