1172113-64-2Relevant academic research and scientific papers
Biomimetic synthesis of dimeric metabolite acremine g via a highly regioselective and stereoselective Diels-Alder reaction
Arkoudis, Elias,Lykakis, Ioannis N.,Gryparis, Charis,Stratakis, Manolis
supporting information; experimental part, p. 2988 - 2991 (2009/12/06)
The dimeric metabolite acremine G was synthesized featuring a highly regioselective and stereoselective Diels-Alder reaction between a TBS-protected hydroquinone diene and a structurally related alkenyl quinone. The major endo [4 + 2] adduct slowly transforms to acremine G by the atmospheric air under the deprotection conditions (in situ generated HF).
