1172134-49-4

Basic information

• Product Name: 9-boraanthracene-H₂IMes
• Synonyms: 9-boraanthracene-H₂IMes
• CAS NO: 1172134-49-4
• Molecular Weight: 482.476
• Mol File: 1172134-49-4.mol

Chemical Properties

• CAS DataBase Reference: 9-boraanthracene-H₂IMes(CAS DataBase Reference)
• NIST Chemistry Reference: 9-boraanthracene-H₂IMes(1172134-49-4)
• EPA Substance Registry System: 9-boraanthracene-H₂IMes(1172134-49-4)

Safety Data

• Hazardous Substances Data: 1172134-49-4(Hazardous Substances Data)

Upstream product

• 1172134-48-3 9-bora-9-chloro-9,10-dihydroanthracene 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene 
• 173035-11-5 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene 
• 23708-65-8 9-bora-9-chloro-9,10-dihydroanthracene 
• 23708-66-9 5,5-dimethyl-5,10-dihydrodibenzo[b,e]stannine 

Downstream Products

• 1172134-50-7 9-bora-9-(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)anthracene oxygen adduct 

Relevant articles and documents

Synthesis and comparative characterization of 9-boraanthracene, 5-boranaphthacene, and 6-borapentacene stabilized by the H2IMes carbene

A general procedure for the preparation of three N-heterocyclic carbene stabilized, boron-containing acenes (9-boraanthracene, 5-boranaphthacene, and 6-borapentacene) is presented. The key steps involve a transmetallation reaction between BCl3 and an appropriate stannacyclic precursor, and the dehydrochlorination of the H2IMes adduct of the chloroborane product. Comparative structural, photophysical, and redox properties reveal narrow HOMO-LUMO gaps relative to the all-carbon acene analogues. Just add boron: Synthetic routes to the N-heterocyclic-carbene-stabilized 5-boranaphthacene and 6-borapentacene are described and complement that previously developed for 9-boraanthracene. Comparative structural, photophysical, and redox properties reveal narrow HOMO-LUMO gaps relative to the all-carbon acene analogues.