117238-41-2Relevant academic research and scientific papers
SYNTHESIS OF METHYLENE BRIDGED C-DISACCHARIDES
Giese, Bernd,Hoch, Monika,Lamberth, Clemens,Schmidt, Richard R.
, p. 1375 - 1378 (2007/10/02)
Addition of glycosyl radicals to the α-methylene lactones 8 obtained from the corresponding glycopyranosyl phenylsulfoxides 5a,b in convenient two step procedures provides methylene bridged C-disaccharides in high diastereoselectivities.Thus, after reduction of the lactone moiety the methylene bridged analogs 9-11 of kojibiose, ristobiose, and α-L-fucopyranosyl(1-2)-D-galactose, respectively, were obtained.
