1172591-42-2

Basic information

• Product Name: 3-(hydroxy(3-iodophenyl)methyl)tetrahydro-2H-pyran-2-one
• Synonyms: 3-(hydroxy(3-iodophenyl)methyl)tetrahydro-2H-pyran-2-one
• CAS NO: 1172591-42-2
• Molecular Weight: 332.138
• Mol File: 1172591-42-2.mol

Chemical Properties

• CAS DataBase Reference: 3-(hydroxy(3-iodophenyl)methyl)tetrahydro-2H-pyran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(hydroxy(3-iodophenyl)methyl)tetrahydro-2H-pyran-2-one(1172591-42-2)
• EPA Substance Registry System: 3-(hydroxy(3-iodophenyl)methyl)tetrahydro-2H-pyran-2-one(1172591-42-2)

Safety Data

• Hazardous Substances Data: 1172591-42-2(Hazardous Substances Data)

Upstream product

• 696-41-3 m-iodobenzaldehyde 
• 130650-09-8 tert-butyl(3,4-dihydro-2H-pyran-6-yloxy)dimethylsilane 

Relevant articles and documents

Catalysis of Mukaiyama aldol reactions by a tricyclic aluminum alkoxide Lewis acid

(Chemical Equation Presented) The Mukayiama aldol reaction of aldehydes is efficiently accomplished with a low concentration of the dimeric alumatrane catalyst 2 at mild or subambient temperatures. Our protocol tolerates a wide variety of electron-rich, neutral, and deficient aryl, alkyl, and heterocyclic aldehydes. A wide variety of enol silyl ethers are also tolerated. An intermediate that was isolated provides mechanistic information regarding the role of dimeric 2 in the Mukaiyama aldol reaction. Experimental evidence is presented for the stronger Lewis acidity of 5 compared with F3B.