1172633-40-7Relevant academic research and scientific papers
Novel stereocontrolled synthesis of highly functionalized cyclobutanes by epoxide opening through a carbanion intermediate in heteroconjugate addition
Adachi, Masaatsu,Yamauchi, Eiji,Komada, Takema,Isobe, Minoru
scheme or table, p. 1157 - 1161 (2009/10/17)
We have demonstrated a new cyclobutane ring formation from the trans-1,2-disubstituted epoxides through intramolecular carbanion opening process. In this reaction, the nucleophilic carbanion is generated not via α-proton abstraction but via heteroconjugat
