1173009-10-3Relevant academic research and scientific papers
Stereoselective functionalization of dihydropyran-3-ols: Application to the synthesis of enantiopure ethyl deoxymonate B
De La Pradilla, Roberto Fernandez,Lwoff, Nadia,Viso, Alma
supporting information; experimental part, p. 2312 - 2322 (2009/08/17)
The behavior of readily available enantiopure cis and trans 3,6-disubstituted dihydropyran-3-ols and derivatives in epoxidation, osmium-catalyzed dihydroxylations, SN2 and Claisen-related processes has been examined. The highly diastereoselective dihydroxylation of a suitably functionalized cis 3,6-disubstituted dihydropyran-3-ol has been used in the synthesis of ethyl deoxymonate B from a 3-sulfinyl- dihydropyran intermediate.
