117306-60-2

Upstream product

• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 
• 1074-82-4 potassium phtalimide 
• 7764-30-9 2,2'-disulfanediylbis(isoindoline-1,3-dione) 
• 75365-64-9 cis-(PPh₃)2Pt(SCH₂Ph)2 
• 136918-14-4 phthalimide 
• 22455-21-6 Pt((C₆H₅)3P)2(OC(CH₃)2OO) 

Relevant academic research and scientific papers

Synthesis and characterization of the disulfanoplatinum complexes cis-(PPh3)2Pt(phth)SSR, where phth = phthalimido and R = CH2Ph, CH2CH2CH3, CHMe2, p-C6H4Me, phth

Disulfano complexes of the type cis-(PPh3)2Pt(phth)SSR, where phth = phthalimido and R = CH2Ph, CH2CH2CH3, CHMe2, 4-C6H4Me, phth, have been prepared via oxidative addition of RSS(phth) to (PPh3)2Pt(C2H4), wherein S-N bond cleavage occurs. Similarly, the thiolato analogues cis-(PPh3)2Pt(phth)SR were obtained by using RS(phth). cis-(PPh3)2Pt(phth)SSR complexes, where R = CH2Ph, phth, are desulfurized by PPh3 to give cis-(PPh3)2Pt(phth)SCH2Ph and cis-(PPh3)2Pt(phth)2, respectively. Treatment of cis-L2Pt(SCH2Ph)2, where L = PPh3, PMePh2, PMe2Ph, with (phth)SS(phth) resulted in stepwise displacement of the phenylmethanethiolato ligands by phthalimido groups to give first cis-L2Pt(phth)SCH2Ph and upon further reaction cis-L2Pt(phth)2 for L = PPh3, PMePh2 accompanied by the formation of organic polysulfanes RSxR, where x = 2-4. At -20 °C trans-(PMe2Ph)2Pt(phth)SCH2Ph was isolated. The complexes cis-L2Pt(phth)2 were also prepared from cis-L2PtCl2 and potassium phthalimide.