1173114-40-3Relevant academic research and scientific papers
Preparation, structure and catalytic activity of copper(II) complexes of novel 4,4′-BOX ligands
Frain, David,Kirby, Fiona,McArdle, Patrick,O'Leary, Patrick
experimental part, p. 4103 - 4106 (2010/08/19)
This Letter details the synthesis of two new 4,4′-bisoxazoline (BOX) ligands. The copper(II) complex of one of the new ligands is structurally determined. The catalytic performance of the copper(II) complexes of the novel ligands, and that of our recently described phenyl AraBOX ligand in Diels-Alder reactions are reported. We have used the structural information to propose an explanation of a curious variation in the diastereoselectivity obtained in the case of one ligand complex.
The synthesis of AraBOX, a new 4,4′-bis(oxazoline), from novel pentitol-derived bis-β-amino alcohols
Frain, David,Kirby, Fiona,McArdle, Patrick,O'Leary, Patrick
experimental part, p. 1261 - 1264 (2009/09/06)
The preparation of a novel phenyl 4,4′-bis(oxazoline) [AraBOX] is described. The novel ligand is prepared in two efficient steps from a bis-[(O-silyl)β-amino alcohol], via conversion into an intermediate bis(benzamide) followed by a one-pot deprotection-a
