117319-08-1

Basic information

• Product Name: P-trans-Cl{Rh(o-diphenylphosphinophenylamine)(CO)Cl}
• CAS NO: 117319-08-1
• Molecular Weight: 443.674
• Mol File: 117319-08-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: P-trans-Cl{Rh(o-diphenylphosphinophenylamine)(CO)Cl}(CAS DataBase Reference)
• NIST Chemistry Reference: P-trans-Cl{Rh(o-diphenylphosphinophenylamine)(CO)Cl}(117319-08-1)
• EPA Substance Registry System: P-trans-Cl{Rh(o-diphenylphosphinophenylamine)(CO)Cl}(117319-08-1)

Safety Data

• Hazardous Substances Data: 117319-08-1(Hazardous Substances Data)

Upstream product

• 65423-44-1 (2-diphenylphosphino)benzeneamine 
• 14593-70-5 N(n-Bu)4{Rh(CO)2Cl₂} 

Downstream Products

• 117319-15-0 mer-Cl,Cl-trans-P-{Rh(PPh₂C₆H₄NH₂)(CO)Cl₃} 

Relevant articles and documents

Synthesis and Oxidation Reactions of Mono- and Di-nuclear Rhodium Carbonyl Complexes of (o-Diphenylphosphinophenyl)amine, H2L; X-Ray Structure Analysis of a Rhodium(II) Amido-bridged Dimer, 2>*EtOH

Reaction of cis-n4> or 2> with one or two molar equivalents of (o-diphenylphosphinophenyl)amine (H2L) respectively gives the mononuclear halogenocarbonylrhodium(I) complexes .These new compounds were found to react with air to give the novel amido-bridged rhodium(II) metal-metal bonded dimers 2> .The chloro species (2a) was also shown to react with base in inert atmosphere to generate the rhodium(I) amido-bridged dimer 2> (4), which reacts with one molar equivalent of halogen to produce (5) or with excess halogen to give the monomeric rhodium(III) mer-trihalogeno complexes .The chloro rhodium(II) dimer (5a) has been characterised by X-ray structure analysis.Crystals of (5a)*EtOH are monoclinic, space group P21/c, with a=14.669(3), b=14.754(3), c=18.233(4) Angstroem, β=92.46(4) degree, and Z=4.Full-matrix refinement of 3498 unique data with I>/=3?(I) (3θ25 degree) gave R=0.045 and R'=0.042.