117343-45-0

Basic information

• Product Name: (1,2-benzisoxazol-3-yl)(p-tolylthio)acetic acid
• Synonyms: (1,2-benzisoxazol-3-yl)(p-tolylthio)acetic acid
• CAS NO: 117343-45-0
• Molecular Weight: 299.35
• Mol File: 117343-45-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1,2-benzisoxazol-3-yl)(p-tolylthio)acetic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (1,2-benzisoxazol-3-yl)(p-tolylthio)acetic acid(117343-45-0)
• EPA Substance Registry System: (1,2-benzisoxazol-3-yl)(p-tolylthio)acetic acid(117343-45-0)

Safety Data

• Hazardous Substances Data: 117343-45-0(Hazardous Substances Data)

Upstream product

• 37924-67-7 α-bromo-1,2-benzisoxazole-3-acetic acid 
• 10486-08-5 sodium p-thiocresolate 

Downstream Products

• 96994-40-0 3-amino-3-benzylchroman-2,4-dione hydrochloride 
• 96994-44-4 methyl 2-benzyl-3-(2-benzyloxyphenyl)aziridine-2-carboxylate 
• 96994-43-3 methyl 2-benzyl-3-(2-benzyloxyphenyl)-2H-azirine-2-carboxylate 
• 117375-36-7 methyl (1,2-benzisoxazol-3-yl)-p-tolylsulphonyl-acetate 
• 101555-32-2 methyl 3-(2-acetoxyphenyl)-2-benzyl-2H-azirine-2-carboxylate 
• 117375-34-5 methyl (1,2-benzisoxazol-3-yl)-p-tolylsulphinyl-acetate 
• 117375-48-1 N-(3-Benzyl-2,4-dioxo-chroman-3-yl)-acetamide 
• 117375-51-6 2-Acetylamino-3-(2-methoxy-phenyl)-2-methyl-3-oxo-propionic acid methyl ester 
• 96994-32-0 methyl 2-benzyl-3-(2-hydroxyphenyl)-2H-azirine-2-carboxylate 
• 89245-65-8 methyl (1,2-benzisoxazol-3-yl)benzylacetate 
• 117375-50-5 Acetic acid 2-(2-acetylamino-propionyl)-phenyl ester 
• 96994-42-2 methyl 2-(2-methoxybenzoyl)alaninate 
• 117375-41-4 4-amino-3-benzylcoumarin 
• 96994-41-1 methyl 3-(2-methoxyphenyl)-2-methyl-2H-azirine-2-carboxylate 

Relevant articles and documents

Halogenation Reaction of S-Aryl-Ssulfoximide

The reactions of the title free sulfoximide with N-bromosuccinimide (NBS) and N-chlorosuccinimide (NCS) afforded the corresponding α-halogenated "free" sulfoximides in good yields.The α-bromination proceeded via a facile N-bromination followed by a bromine transfer reaction of the resulting N-bromosulfoximide.The NCS chlorination, in contrast, proceeded via direct α-chlorination, not via N-chlorination.However, in the presence of potassium carbonate or silica gel N-chlorination occured predominantly in the NCS chlorination.Keywords---1,2-benzisoxazole; halogenation; N-halosulfoximide; α-halo sulfoximide; rearrangement; induction period