117438-63-8Relevant academic research and scientific papers
Design and synthesis of new ferroelectric liquid crystals. 5.1 properties of some chiral fluorinated FLCs: A direct connection between macroscopic properties and absolute configuration in a fluid phase
Walba,Razavi,Clark,Parmar
, p. 8686 - 8691 (1988)
In combination with the 'bent cylinder binding site' model for the molecular origins of the ferroelectric polarization P in ferroelectric liquid crystals (FLCs), the observed sign and magnitude of P in mixtures of nonracemic guests with a low-polarization
Chemoselective addition of in situ prepared lithium alkynyl borates to aldehydes: a practical and transition metal free approach toward the synthesis of propargylic alcohols
Francesco, Irene Notar,Renier, Antoine,Wagner, Alain,Colobert, Fran?oise
experimental part, p. 1386 - 1389 (2010/04/25)
A convenient synthesis of functionalized propargylic alcohols arising from the 1,2-addition of lithium alkynyl-trimethyl borate onto aldehydes under transition metal free mild conditions is reported. The reaction tolerates a wide range of functional groups, is highly chemoselective and the propargylic alcohols are isolated in good to excellent yields.
