1174457-95-4

Basic information

• Product Name: carbonofluoridoylperoxy trifluoromethyl carbonate
• Synonyms: carbonofluoridoylperoxy trifluoromethyl carbonate
• CAS NO: 1174457-95-4
• Molecular Weight: 208.023
• Mol File: 1174457-95-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: carbonofluoridoylperoxy trifluoromethyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: carbonofluoridoylperoxy trifluoromethyl carbonate(1174457-95-4)
• EPA Substance Registry System: carbonofluoridoylperoxy trifluoromethyl carbonate(1174457-95-4)

Safety Data

• Hazardous Substances Data: 1174457-95-4(Hazardous Substances Data)

Upstream product

• 359-40-0 oxalyl difluoride 
• 201230-82-2 carbon monoxide 
• 407-25-0 trifluoroacetic anhydride 

Relevant articles and documents

Synthesis and properties of trifluoromethoxyl fluoroformyl anhydride, CF3OC(O)OC(O)F

In the present work the synthesis of the trifluoromethoxyl fluoroformyl anhydride is presented for the first time. Two strategies were employed to obtain CF3OC(O)OC(O)F: the thermal decomposition of CF 3OC(O)OOOC(O)F in excess of CO, and the reaction between CF 3OC(O)OOC(O)F, FC(O)OOC(O)F and CO. A mechanism was proposed taking into account reaction rates and thermal stability of the intermediates. DFT calculations at B3LYP/6-311+G* level were used to explore the conformational space of this molecule and the relative populations of conformers at room temperature, and to simulate the experimental vibrational spectrum. This molecule completes the family of the asymmetric oxygen bonded acyl compounds CF3OC(O)OxC(O)F with x = 1-3.