1174637-69-4

Basic information

• Product Name: C₁₄H₁₈BrNO₄
• Synonyms: C₁₄H₁₈BrNO₄
• CAS NO: 1174637-69-4
• Molecular Weight: 344.205
• Mol File: 1174637-69-4.mol

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₈BrNO₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₈BrNO₄(1174637-69-4)
• EPA Substance Registry System: C₁₄H₁₈BrNO₄(1174637-69-4)

Safety Data

• Hazardous Substances Data: 1174637-69-4(Hazardous Substances Data)

Upstream product

• 1174637-67-2 C₁₂H₁₇NO₃ 
• 598-21-0 2-Bromoacetyl bromide 
• 56613-80-0 D-2-phenylglycinol 

Downstream Products

• 1174637-71-8 (R)-(-)-{[(2-hydroxy-1-phenyl-ethyl)-(2-methoxycarbonyl-ethyl)-carbamoyl]-methyl}-dimethyl-sulfonium bromide 

Relevant articles and documents

Chiral cyclic zwitterionic bipyridinium-4-olates for the diastereoselective synthesis of (R,S)- A nd (S,R)-trozamicol

A series of new chiral enantiopure cyclic zwitterionic bipyridinium-4-olates compounds were prepared in four steps starting from the corresponding primary chiral amine. With these intermediates, a convenient methodology has been developed for the synthesis of cis-3-piperidinyl-4-hydroxypiperidines. Specifically, the utility of this chiral zwitterionic type intermediate has been demonstrated by the synthesis of (R,S)- A nd (S,R)-trozamicol.

New cyclic zwitterionic building blocks for the synthesis of piperidine-2,4-dione and pyridine-2-one compounds

In this Letter we describe the synthesis of new chiral cyclic zwitterionic pyridin-2-one compounds 5a,b via an intramolecular ring-closure reaction of a stabilize amide sulfur ylide 4a,b derived from (R)-(-)-2-phenylglycinol and (R)-(+)-phenylethylamine i