1174708-87-2Relevant academic research and scientific papers
Aerobic oxysulfonylation of alkenes using thiophenols: An efficient one-pot route to β-ketosulfones
Singh, Atul K.,Chawla, Ruchi,Keshari, Twinkle,Yadav, Vinod K.,Yadav, Lal Dhar S.
, p. 8550 - 8554 (2014)
We have developed a highly efficient synthetic route to β-ketosulfones via AgNO3 catalyzed oxysulfonylation of alkenes using thiophenols in the presence of air (O2) and K2S2O8 as eco-friendly oxidants. Thiophenols have been used as sulfonylation precursors for the first time in a dioxygen activation based radical process. Moreover, the protocol also offers a new and convenient method for the synthesis of β-hydroxysulfides at room temperature without the use of any initiator. This journal is
Rongalite promoted highly regioselective synthesis of β-hydroxy sulfides by ring opening of epoxides with disulfides
Guo, Wenxue,Chen, Jiuxi,Wu, Dengze,Ding, Jinchang,Chen, Fan,Wu, Huayue
experimental part, p. 5240 - 5243 (2009/11/30)
Rongalite promotes cleavage of disulfides generating thiolate anions that then undergo facile ring opening of epoxides in the presence of K2CO3 to afford α-addition products 3 with good to excellent yields. The important f
